[N-(8-Quinolylmethyl)iminodiethanol-κ4 N,N′,O,O′]bis(thiocyanato-κN)nickel(II) monohydrate
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چکیده
In the neutral title complex, [Ni(NCS)(2)(C(14)H(18)N(2)O(2))]·H(2)O, the Ni(II) ion has a distorted octa-hedral geometry with cis-isothio-cyanate ligands.
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Diaquabis[bis(pyrazin-2-yl) sulfide-κN 4]bis(thiocyanato-κN)iron(II) monohydrate
In the title compound [Fe(NCS)2(C8H6N4S)2(H2O)2]·H2O, the Fe(II) cation is coordinated by two N-bonded thio-cyanate anions, two N (4)-bonded bis-(pyrazin-2-yl) sulfide ligands and two water mol-ecules in an slightly distorted octa-hedral geometry. The Fe(II) cation is located on a center of inversion and the lattice water mol-ecule on a twofold rotation axis. The thio-cyanate anions, the coordi...
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In the title mononuclear complex, [Ni(NCS)(2)(C(12)H(8)N(4)S)(2)(H(2)O)(2)]·2H(2)O, the Ni(II) atom is located on an inversion center and is octa-hedrally coordinated by four N atoms from two 2,5-di-4-pyridyl-1,3,4-thia-diazole (bpt) ligands and two thio-cyanate mol-ecules forming the equatorial plane; the axial positions are occupied by two O atoms of coordinated water mol-ecules. O-H⋯O, O-H⋯N...
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In the title compound, [Co(NCS)(2)(C(16)H(16)N(4)O(2))](n), the octa-hedrally coordinated Co(II) ion lies on a crystallographic inversion center, with trans isothio-cyanate ligands. Pyridyl N-donor atoms and formyl O-donor atoms from exotetra-dentate bis-(4-pyridyl-carbon-yl)piperazine (4-bpfp) ligands link the Co(NCS)(2) units into a [Co(NCS)(2)(4-bpfp)](n) coordination polymer layer that is o...
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In the centrosymmetric mononuclear title complex, [Ni(NCS)(2)(C(11)H(11)N(3)O)(4)], the Ni(II) atom, located on an inversion centre, is hexa-coordinated in a distorted octa-hedral geometry comprising four N atoms of four monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands and two N atoms from thio-cyanate anions.
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The centrosymmetric binuclear complex, [Cu(2)(C(13)H(13)N(2)O)(2)(NCS)(2)], formed via phenolate oxygen bridges, involves the Cu(II) atoms in a distorted square-pyramidal coordination [τ = 0.197 (1)]. A Cu⋯Cu separation of 3.2281 (3) Å is observed. The in-plane Cu-O(phenolate) distance [1.9342 (8) Å] is shorter than the axial distance [2.252 (8) Å]. The Cu-N(amine) and Cu-N(py) distances are si...
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